Conformable retroreflective graphic film

ABSTRACT

The present disclosure provides a retroreflective film for removable application to a three-dimensional object. The film comprises a transparent film layer; a first transparent adhesive layer; a retroreflective layer comprising glass microspheres and a binder; a metalized coating layer comprising aluminum applied on the retroreflective layer; a removable adhesive layer having a peel force of 2 lbs/inch or less. When the film is elongated by 50% it retains at least 50% of its unstretched coefficient of retroreflection as measured at the 0.2 degree observation angle and −4 degree entrance angle. When the film is elongated by 50% it retains at least 50% of its unstretched gloss when measured at a 20 degree angle.

CROSS REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. application Ser. No.15/352,623, filed Nov. 16, 2016, now allowed, the disclosure of which isincorporated by reference in their entirety herein.

FIELD OF INVENTION

The present invention relates to wrappable, conformable film that isretroreflective and can be removably applied to a three-dimensionalobject, such as a vehicle.

BACKGROUND

Graphic films are used in a variety of applications, such asinstallation on an interior or exterior surface of a building, vehicleor other structure. A variety of types and finishes for graphic filmsexist, including colored, matte, glossy, textured and in some instancesreflective and even retroreflective. It can be difficult to apply orinstall a graphic film that is retroreflective on a three dimensional orcomplex surface. Effective installation of such a film requires the filmto be stretched, and sometimes removed, repositioned, and applied asecond time. These variables in film handling often result in visualdefects in the film, such as dark or dull spots.

SUMMARY

The present invention provides an improved retroreflective graphic filmthat more effectively maintains surface gloss and retroreflectivityvalues after being stretched. Additionally, the present disclosureprovides a retroreflective film where retroreflectivity can be at leastpartially restored after the film is damaged through the application ofheat. This allows retroreflective films consistent with the presentdisclosure to be installed on vehicles resulting in fewer dark spotscreated by handling during installation and restoration ofretroreflectivity in damaged film areas.

In one instance, the present disclosure provides a retroreflective filmfor removable application to a three-dimensional object. The filmcomprises a transparent film layer; a first transparent adhesive layer;a retroreflective layer comprising glass microspheres and a binder; ametalized coating layer comprising aluminum applied on theretroreflective layer; and a removable adhesive layer having a peelforce of 2 lbs/inch or less. When the film is elongated by 50% itretains at least 50% of its unstretched coefficient of retroreflectionas measured at the 0.2 degree observation angle and −4 degree entranceangle.

In another instance, the present disclosure provides a retroreflectivefilm for removable application to a three-dimensional object. The filmcomprises a transparent film layer; a first transparent adhesive layer;a retroreflective layer comprising glass microspheres and a binder; ametalized coating layer comprising aluminum applied on theretroreflective layer; and a removable adhesive layer having a peelforce of 2 lbs/inch or less. When the film is elongated by 50% itretains at least 50% of its unstretched gloss when measured at a 20degree angle and in the machine direction.

In some embodiments, the removable adhesive has a peel force of 1.5lb/inch or less.

In some embodiments, the removable adhesive layer comprises channelsthat define exit pathways to provide a fluid egress to a periphery ofthe film when the film is applied to a three-dimensional object.

In some embodiments, the removable adhesive layer comprises posts in theadhesive to allow slidability.

In some embodiments, the film further comprises a graphic printed ontothe transparent film layer.

In some embodiments, the film has a total thickness in the range of 5 to8 mils.

In some embodiments, the removable adhesive layer is a pressuresensitive adhesive.

In some embodiments, the film further comprises a structured removableliner adjacent to the removable adhesive layer.

In some embodiments, when the film is elongated by 50% it retains atleast 50% of its gloss when unstretched as measured at a 20 degree angleand in the machine direction.

In some embodiments, when the film is elongated by 50%, it retains atleast 90% of its gloss when measured unstretched at a 60 degree angle inthe machine direction.

In some embodiments, when the film is elongated by 50%, it retains atleast 70% of its gloss when measured unstretched at a 20 degree angle inthe machine direction.

BRIEF DESCRIPTION OF THE DRAWINGS

The invention may be more completely understood in consideration of thefollowing detailed description of various embodiments of the inventionin connection with the accompanying drawings, in which:

FIG. 1 is an exemplary portion of a cross section of a retroreflectivefilm consistent with the present disclosure.

FIG. 2 is an exemplary portion of a cross section of a retroreflectivefilm with structured adhesive features and a liner.

FIGS. 3A-3E show an exemplary sequence of images illustrating bruisingor damaging and restoration of the retroreflectivity of a filmconsistent with the present disclosure.

FIG. 4 shows an Irwin QUICK-GRIP SL300 one-handed bar clamp/spreadermodified for use as a spreader for use in testing exemplary samples.

It is to be understood that the embodiments may be utilized andstructural changes may be made without departing from the scope of theinvention. The figures are not necessarily to scale. Like numbers usedin the figures refer to like components. However, it will be understoodthat the use of a number to refer to a component in a given figure isnot intended to limit the component in another figure labeled with thesame number.

DETAILED DESCRIPTION

FIG. 1 is an exemplary portion of a cross section of a retroreflectivefilm 100 consistent with the present disclosure. FIG. 1 shows the layersof a film in the order they would appear when the film is applied to athree-dimensional object 101. Object 101 may be any surface to which aremovable retroreflective film may be applied. For example, object 101may include interior or exterior surfaces of a building, a vehicle, orany other object. The surface of object 101 may be made of any type ofmaterial, including but not limited to plastic, metal, wood, brick,stone, cement or concrete.

Layer 150 is a transparent film layer. Layer 150 may be made of anysuitable compliant film that is stretchable and transparent. Suitablefilms include, for example, vinyl, polyvinyl chloride, plasticizedpolyvinyl chloride, polyurethane, polyethylene, polypropylene,fluororesin or the like. The thickness of layer 150 may vary widelydepending upon the desired application, but is usually in a range of 12mils or less, and may preferably be in the range of 1 mil to three mils.Layer 150 is transparent such that it allows light to pass through it sothat objects behind it can be clearly seen. Layer 150 may be compliantsuch that when it is stretched, the film does not recover to itsoriginal length without the application of heat.

In some instances, a graphic or image may be printed on layer 150 usingany known printing methods, such as ink jet printing (solvent, latex, UVinks, etc.), solvent printing, screen printing (solvent inks, UV inks,etc.) and gravure printing. The retroreflectivity of a graphic printedon the film will depend upon the transparency of the inks used and howmuch ink is deposited on the film.

In some instances, an optional protective film layer (or overlaminate)may be laminated over layer 150 to protect the exterior surface of thefilm or a graphic or image printed on layer 150. A protective film layermay have the same composition and thickness as layer 150. Adhesive orheat may be used to laminate an optional protective layer to film 150.

Layer 140 is a transparent adhesive layer. Examples of adhesive that maybe used for layer 140 include any suitable pressure sensitive adhesive.Classes of suitable pressure sensitive adhesives include acrylics,tackified rubber, tackified synthetic rubber, ethylene vinyl acetate andthe like. Suitable acrylic adhesives are disclosed, for example, in U.S.Pat. Nos. 3,239,478; 3,935,338; 5,169,727; 4,952,650 and 4,181,752,incorporated herein by reference.

In some instances, a primer may be optionally coated on film layer 150before adhesive layer 140 is applied to enhance the bond between thefilm and the adhesive. The type of primary will vary with the type offilm and adhesive used. Examples of suitable primers include chlorinatedpolyolefins, polyamides and modified polymers such as those disclosed inU.S. Pat. Nos. 6,677,376 and 5,623,010, and other modified acrylicpolymers. Typically primers are dispersed into an adequate solvent invery low concentrations (such as less than about 5% solids) and coatedonto the film, and dried at room temperature or an elevated temperatureto form a very thin layer. Typical solvents may include water, heptane,toluene, acetone, ethyl acetate, isopropanol and the like, used alone oras blends thereof.

Layer 130 is a retroreflective layer. In one instance, layer 130 isadjacent to adhesive layer 140. Layer 130 comprises glass microspheresin a resin (also referred to as a binder). Examples of suitable resinmaterials include polyvinyl butyral, aliphatic polyurethane andpolyurethane extended polyethylene terephthalate (PET) polymers (e.g.,described at column 15, lines 30-35 of U.S. Pat. No. 5,882,771,incorporated herein by reference). The microspheres may be glass andapproximately 60 microns in diameter, but could range in size from 40 to90 microns. Microspheres are disposed substantially as a monolayerwithin the resin. The resin creates a spacing layer around (on all sidesof) the microspheres.

When layer 130 is coated with metalized coating 120, light passingthrough transparent film layer 150, transparent adhesive layer 140 andretroreflective layer 130 is then reflected by metalized coating layer120 back through each of the three preceding layers. In order to achieveoptimum retroreflection (light rays striking a surface and beingdirected back to the source of light) the binder in layer 130 achievesgood cupping around the microspheres to form a spacing layer between themicrospheres and the metalized coating. Good cupping occurs when ahigher proportion of the metalized coating is positioned at a curvedplane where light rays that pass through an individual microsphere arefocused. Good cupping is generally achieved by greater penetration ofthe spacing layer between adjacent microspheres and also by the use ofpolymeric materials or solutions of appropriate viscosity or flowcharacteristics. Good cupping is indicated by measurements ofmicroroughness on the back of the retroreflective layer 130 or on theback of the metalized coating layer 120. Generally, good cupping has amicroroughness reading of about 125 microinches, on average, or morewhen measured on a Bendix portable Profilometer using a2.5-micrometer-radius diamond stylus. The desired microroughness variessomewhat with the size of the microspheres and can be 5 or 10 percenthigher for larger microspheres.

Metalized coating layer 120 can be coated onto retroreflective layer 130using any suitable method, such as physical vapor deposition (PVD)(a.k.a. “vapor coating”). Metalized coating layer 120 may be made of anysuitable materials, such as aluminum, tin, or silver.

Layer 110 is a removable adhesive layer such that the film 100 can beremoved from object 101 without leaving adhesive residue, and withoutthe use of any chemical removal aids. Adhesive layer 110 may be any typeof pressure sensitive adhesive with a suitable peel force. For example,in one instance, adhesive layer 110 may have a peel force of less than 2lbs/inch or less, or preferably, less than 1.5 lbs/inch or less. Anexample of a suitable pressure sensitive adhesive is 3M™ RemovableRepositionable Adhesive 1000, as used in 3M™ Repositionable Tape 9449S,among others.

In some instances layer 110 may comprise channels that define exitpathways to provide a fluid egress to a periphery of the film when thefilm is applied to a three-dimensional object. In some instances, layer110 may alternately or additionally comprise posts in the adhesive toallow slideability. Such adhesive features are described in furtherdetail, for example in U.S. Pat. Nos. 6,197,397 and 5,897,930,incorporated herein by reference.

While layers 110, 120, 130, 140 and 150 are shown as directly adjacentto each other in FIG. 1, intervening layers may also be within the scopeof the present disclosure and will be apparent to one of skill in theart upon reading the present disclosure. For purposes of illustration,in some instances primers may be used in conjunction with adhesivelayers, multiple adhesive layers may be used in the place of a singleadhesive layer, and multiple layers of metalized coating may be used inthe place of a single layer of a metalized coating.

The total thickness of film 100, including layers 110, 120, 130, 140 and150 may range depending on the particular materials chosen for each filmlayer. In one instance, film 100 may have a thickness in the range of 2mils to 10 mils. In another instance, film 100 may have a thickness inthe range of 5 mils to 8 mils.

FIG. 2 is an exemplary portion of a cross section of a retroreflectivefilm 200 with structured adhesive features and a removable release liner230. Retroflective film 210 includes multiple layers, such as layers120, 130, 140 and 150 as shown in FIG. 1. Adhesive layer 220 is aremovable adhesive, similar to adhesive layer 110 in FIG. 1. Adhesivelayer 220 includes structures such as channels 224 and posts 225.Channels 224 and posts 225 can be formed by laminating retroflectivefilm 210 and removable adhesive 220 to structured liner 230 withsufficient force that the structures 232 and 234 displace the adhesiveto form complementary structures within adhesive layer 220. In anothermethod of manufacture, adhesive layer 220 may be cast onto structuredliner 230. Structured liner 230 and adhesive layer 220 may then belaminated to retroreflective film 210. Other methods for creatingstructures in adhesive layer 220 are discussed in further detail in U.S.Pat. No. 5,650,215, incorporated herein by reference.

Structured liner 230 may be made of a paper or plasticized material thatis typically coated with a release coating, such as a silicone, to alloweasy removal of structured liner 230 from retroreflective film 210 andadhesive 220 so that retroreflective film 210 with adhesive 220 can beconveniently applied to a three dimensional object with the benefit ofposts 225 to allow positionability and channels 224 to provide airegress during the application process.

FIGS. 3A-3E show an exemplary sequence of images illustrating bruisingor damaging and restoration of the retroreflectivity of a filmconsistent with the present disclosure. As described herein, one of theadvantages of the present invention is providing a film that can berestored after bruising (or damaging of the retroreflective propertiesof the film) occurs during installation of the film onto an object.Bruising can occur quite easily, particularly during application of thefilm onto a three-dimensional object that requires stretching of thefilm to conform to the surface of the object.

FIG. 3A shows retroreflective film 300 partially applied to the surfaceof vehicle 320. A portion of film 300 not applied to vehicle 320 hasbeen bruised by applicator 340 applying directed pressure to the surfaceof film 300. The darker color of the bruised area 310 is created by thelack of retroreflection in the bruised area 310.

FIG. 3B shows retroreflective film 300 almost entirely applied tovehicle 320. Pressure has been applied by applicator 340 to create abruised area 310 in the shape of the characters “3M”. The applicator 340is applying pressure to the surface of the film using squeegee 350. Thispressure activates the pressure sensitive adhesive on the back side offilm 300 to secure the film 300 to the vehicle 320.

FIG. 3C shows the applicator applying heat to the surface of the film300 after the film 300 has been applied to vehicle 320 using heat gun330. In the example shown, heat gun 330 is capable of producing air witha temperature range from 500° F. to 750° F., though heat guns with abroader temperature ranged may be used consistent with the presentdisclosure. Heat gun 330 was be positioned approximately 1″ to 3″ awayfrom the surface of the film 300, while slowly moving the heat gun 330within a small area for approximately 10 to 20 seconds, or until thebruised area 310 had visually recovered FIG. 3C shows that theright-hand side of the bruising in the shape of the “M” is beginning todiminish after application of heat. FIG. 3D shows increased reduction ofbruising after further application of heat using heat gun 330. FIG. 3Eshows a recovered bruised area 370, after heat has been applied to thefilm 300. A recovered bruised area may not regain the same level ofretroreflectivity the film provided prior to stretching, bruising orapplication to a vehicle. However, a recovered bruised area does notappear different to an unaided eye viewing the retroreflective film inthe dark environment with a light source reflecting off of the film, thelight source and observer both being a distance of approximately tenfeet from the film.

Examples

Retro-reflective graphic films were made and tested for gloss andretro-reflective properties before and after heat stretching. Adhesionwas also tested. These examples are merely for illustrative purposesonly and are not meant to be limiting on the scope of the appendedclaims.

Test Methods: Coefficient of Retro-Reflection Test

A RoadVista Model 932 Field Retroreflectometer (manufactured byRoadVista, San Diego, Calif.) was used in accordance with ASTM TestMethod E1709-09, Standard Test Method for Measurement of RetroreflectiveSigns Using a Portable Retroreflectometer at a 0.2 Degree ObservationAngle, to measure the Coefficient of Retro-reflection of the filmsamples. The film samples (2 inches wide by 2.75 inches long, afterbeing applied to aluminum panels which are available from Q-Lab Corp.Westlake, Ohio available as Q-PANEL number ED-2.75×11NH, using 5052H38Bare Aluminum, 0.025″×2.75″×11″, Etch & Desmut panels) were measured atthe 0.2° observation angle and −4° entrance angle, averaging 4 readingsper sample. Percent (%) Retention for the Coefficient ofRetro-reflection was calculated by dividing the average value of theCoefficient of Retro-reflection (measured incandlepower/foot-candle/square foot) from a 50% stretch sample by theaverage value of the Coefficient of Retro-reflection from an unstretchedsample of the same film.

Gloss Test

A micro-TRI-gloss 4446 (available from BYK-Gardner USA) was usedaccording to ASTM Test Method D523-14, Standard Test Method for SpecularGloss, to measure 20° and 60° Gloss Values. The same test panels thatwere used for measuring the Coefficient of Retro-reflection were usedfor gloss measurements. Measurements were made at 20° and 60° with theinstrument oriented so its long dimension was running parallel with themachine direction of the film on the test panel (3 measurements persample) (referred to as “Machine Direction”). Measurements were alsomade at 20° and 60° with the instrument oriented so its long dimensionwas running parallel with the cross direction of the film on the testpanel (3 measurements per sample) (referred to as “Cross Direction”).Percent (%) Retention for the 20° and 60° Gloss values was calculated bydividing the average Gloss value (recorded as percent of light returnedto the detector) from the 50% stretch sample by the average value froman unstretched sample of the same film.

90° Peel Adhesion Test

An INSTRON model 5564 extensometer (available from INSTRON, Norwood,Mass.) was used in accordance with ASTM Test Method D6862-11, StandardTest Method for 90 Degree Peel Resistance of Adhesives. A 1-inch widesample of the unprinted test film was applied to an aluminum panel(available from Q-Lab Corp. Westlake, Ohio as Q-PANEL numberED-2.75×11NH, using 5052H38 Bare Aluminum, 0.025″×2.75″×11″, Etch &Desmut panels). Then the applied sample was conditioned for 24 hrs (±2hrs.) at 73.4° F. (±2° F.) with relative humidity of 50% (±2%). The filmsample was peeled off the panel, using a peel speed of 12 inches/min,and a 90° peel angle. Results from 3 tests were averaged for eachsample. Results were recorded in lb/in.

Example Preparation

The following film samples were prepared for evaluation:

Example Description E1 Retro-reflective film samples were prepared bythe following process: The retro-reflective base material film (element18 in FIG. 1) of U.S. Pat. No. 4,664,966 Example 1 (incorporated hereinby reference), was coated, on the aluminum vapor coated side of theretro-reflective base film, with a very thin layer of a solvent-basedadhesion promoter (available from 3M Company St. Paul MN as 3M TapePrimer 94). After the solvent dried, the thickness of the coating wasvery thin, similar to a vapor coating thickness. Next, two layers oftransfer adhesive (available from 3M Company St. Paul MN as 3MRepositionable Tape 9449S), were laminated to the retro-reflective basefilm, laminating the transfer adhesive against the side that was coatedwith the adhesion promoter. Next, the above sample was laminated onto amicro-structured, silicone coated release liner. The adhesive side ofthe film sample pressing against the silicone side of the release liner(available from 3M Company St. Paul MN, as the release liner used on 3MPrint Wrap Film IJ180mC-10). Finally, the above sample was laminated (onthe retro-reflective film side) with a clear polyvinylchloride film witha pressure sensitive adhesive (available from 3M Company St. Paul MN as3M SCOTCHCAL Luster Overlaminate 8519). To ensure proper bonding betweenthe film and adhesive layers, this completed sample construction wasthen baked at 150° F. (± 5° F.) for 30 minutes (± 5 minutes), prior touse in any testing. CE1 Retro-reflective film available from 3M Company,St. Paul MN as 3M SCOTCHLITE Reflective Graphic Film 680-10 White

Unstretched

Samples of these films (2 inches wide by 2.75 inches long) were appliedto aluminum panels (available from Q-Lab Corp. Westlake, Ohio as Q-PANELnumber ED-2.75×11NH, using 5052H38 Bare Aluminum, 0.025″×2.75″×11″, Etch& Desmut panels) and tested using the methods described above. Resultsare reported in Table 1.

Stretched

An Irwin QUICK-GRIP SL300 One-handed bar clamp/spreader (available fromIrwin Tools Huntersville, N.C.) and shown in FIG. 4 was modified for useas a spreader, with an aluminum block 430 attached to the clamp I-beam440 and another aluminum block 420 attached to the movable handle 410 toallow mounting of a film sample. A 2″×7.5″ sample of the adhesive coatedtest film with the release liner removed was applied across the topedges of the aluminum blocks. The sample was centered across the openarea (5.25″ wide). The ends of the strip that extend beyond the aluminumblocks were applied to the sides of the aluminum blocks, so the samplewas held securely on the aluminum blocks. The spreader with the filmattached was placed in a batch oven, set at 150° F. (±5° F.), for 60seconds (±5 seconds). Within 5 seconds from removal from the oven, thespreader's handle was squeezed at a rate of about one second persqueeze. The handle was repeatedly squeezed until the aluminum blockswere 7.875″ apart (or at the 150% mark 450). This point representing a50% stretch relative to the initial starting point of 5.25″. While thestretched film sample was still attached to the spreader, an aluminumpanel (available from Q-Lab Corp. Westlake, Ohio as Q-PANEL numberED-2.75×11NH, using 5052H38 Bare Aluminum, 0.025″×2.75″×11″, Etch &Desmut panels) was positioned under the sample, in the center of thestretched area. Then the stretched film sample was applied to the testpanel, making sure it was applied without any air bubbles under thefilm. The samples were tested using the methods described above. Resultsare reported in Table 1.

Test Results:

TABLE 1 Percent Retention of Retro-reflection, Percent Retention ofGloss, and Adhesion Results % Retention for 20° % Retention for Gloss %Retention for % Retention for 60° % Retention for 60° Average 90° PeelCoefficient of (Machine 20° Gloss (Cross Gloss (Machine Gloss (CrossAdhesion from E&D Example Retro-reflection Direction) Direction)Direction) Direction) Aluminum (lb/in) E1 51% 80% 82% 99% 85% 0.8 CE110% 42% 38% 82% 59% 3.7

What is claimed is:
 1. A retroreflective film for removable applicationto a three-dimensional object comprising: a transparent film layer; afirst transparent adhesive layer; a retroreflective film layercomprising glass microspheres and a binder; a metalized coating layercomprising aluminum applied on the retroreflective layer; a removableadhesive layer having a peel force of 2 lbs/inch or less; wherein whenthe film is elongated by 50% it retains at least 50% of its unstretchedgloss when measured at a 20 degree angle and in the machine direction.2. The film of claim 1, wherein the removable adhesive has a peel forceof 1.5 lb/inch or less.
 3. The film of claim 1, wherein the removableadhesive layer comprises channels that define exit pathways to provide afluid or air egress to a periphery of the film when the film is appliedto a three-dimensional object.
 4. The film of claim 1, wherein theremovable adhesive layer comprises posts in the adhesive to allowslidability.
 5. The film of claim 1, further comprising a graphicprinted onto the transparent film layer.
 6. The film of claim 1, whereinthe film has a total thickness of 5 to 8 mils.
 7. The film of claim 1,wherein the removable adhesive layer is a pressure sensitive adhesive.8. The film of claim 1, wherein when the film is elongated by 50%, itretains at least 90% of its gloss when measured unstretched at a 60degree angle in the machine direction.
 9. The film of claim 1, whereinwhen the film is elongated by 50%, it retains at least 70% of its glosswhen measured unstretched at a 20 degree angle in the machine direction.